Ethyl (Z)-4-ferrocenyl-2-(4-hydroxyanilino)-4-oxobutenoate
نویسندگان
چکیده
منابع مشابه
Ethyl (Z)-4-ferrocenyl-2-(4-hydroxyanilino)-4-oxobutenoate
In the title compound, [Fe(C(5)H(5))(C(17)H(16)NO(4))], the O=C-C=C-N mean plane is twisted with respect to the mean planes of the benzene and substituted cyclo-penta-dienyl rings by 44.2 (2) and 13.8 (3)°, respectively. Furthermore, the O=C-C=C-N mean plane and the O=C-O(ester) plane make a dihedral angle of 55.5 (6)°. Consistent with this large dihedral angle, the linking C-C bond [1.507 (6) ...
متن کامل(Z)-3-Ferrocenyl-2-(4-pyridyl)propenenitrile
In the title compound, [Fe(C(5)H(5))(C(13)H(9)N(2))], the pyridine ring makes a dihedral angle of 9.91 (17)° with the substituted cyclo-penta-dienyl ring and the double bond adopts a Z configuration. In the crystal structure, inter-molecular C-H⋯N hydrogen bonds link the molecules into a one-dimensional chain in the a+c direction.
متن کامل(Z)-Ethyl 4-chloro-2-[(4-chlorophenyl)hydrazono]-3-oxobutanoate
The title compound, C(12)H(12)Cl(2)N(2)O(3), crystallizes as a non-merohedral twin with a twinning ratio of 0.51:0.49. The mol-ecule adopts a keto-hydrazo tautomeric form stabilized by an intra-molecular N-H⋯O hydrogen bond. The configuration around the N-N bond is trans.
متن کاملEthyl (Z)-2-(4-chlorobenzylidene)-3-oxobutanoate
The C=C double-bond in the title compound, C(13)H(13)ClO(3), has a Z configuration. The aliphatic substituents at one end of the double bond, i.e. the CH(3)CO- and C(2)H(5)O(2)C- groups, are aligned at 82.1 (3)° with respect to each other.
متن کاملEthyl and isopropyl 4-ferrocenyl-benzoate.
The title compounds, [Fe(C(5)H(5))(C(14)H(13)O(2))] and [Fe(C(5)H(5))(C(15)H(15)O(2))], respectively, contain the ferrocenyl eta(5)(C(5)H(4)) and phenylene -C(6)H(4)- rings in a nearly coplanar arrangement, with interplanar angles of 6.88 (12) and 10.5 (2) degrees, respectively. Molecules of the ethyl ester form dimers through eta(5)(C(5)H(5))C-H...O=C hydrogen bonds, with graph set R(2)(2)(20)...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811047763